System | 3H4 → 1D2 | 3H4 → 3P0 | 3H4 → 3P1 | 3H4 → 3P2 | T2 | T3 | T4 |
Pobs (Pcal) | Pobs (Pcal) | Pobs (Pcal) | Pobs (Pcal) | ||||
1. Solvent:CH3CN | |||||||
L = GTP | |||||||
Pr(III) | 2.441861 | 0.8824 | 0.4164 | 0.7152 | −2.339 | 1.8407 | 6.5293 |
| (2.441861) | (0.6527) | (0.6426) | (0.7152) |
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Pr(III): L | 2.654619 | 0.8997 | 0.4304 | 0.7078 | −61.08 | 0.2501 | 8.0601 |
| (2.654619) | (0.6713) | 0.6598 | (0.7078) |
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Pr(III): L: Ca(II) | 2.728307 | 0.9066 | 0.4393 | 0.7601 | −47.55 | 0.2576 | 8.9726 |
| (2.728307) | (0.6739) | (0.6625) | (0.7601) |
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2. Solvent: CH3OH | |||||||
L = GTP | |||||||
Pr(III) | 2.649057 | 0.7866 | 0.3978 | 0.7668 | 1.4253 | 1.623 | 8.2898 |
| (2.649057) | (0.5953) | (0.5761) | (0.7668) |
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Pr(III): L | 2.933212 | 0.7998 | 0.4139 | 0.7881 | −53.78 | 1.799 | 9.1772 |
| (2.933212) | (0.6109) | (0.6073) | (0.7881) |
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Pr(III): L: Ca(II) | 2.945997 | 0.8312 | 0.4237 | 0.8035 | −35.2 | 1.912 | 9.642 |
| (2.945997) | (0.6232) | (0.6122) | (0.8035) |
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3. Solvent: Dioxane | |||||||
L = GTP | |||||||
Pr(III) | 2.629602 | 0.7323 | 0.4166 | 0.7649 | 2.1298 | 1.5906 | 8.3253 |
| (2.629602) | (0.5826) | (0.5737) | (0.7649) |
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Pr(III): L | 2.692734 | 0.7676 | 0.4445 | 0.8422 | −101.1 | 1.9843 | 9.4772 |
| (2.692734) | (0.5987) | (0.5833) | (0.8422) |
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Pr(III): L: Ca(II) | 3.809138 | 0.8227 | 0.4677 | 0.9218 | −91.77 | 1.9986 | 9.7447 |
| (3.809138) | (0.6472) | (0.6436) | (0.9218) |
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4. Solvent: DMF | |||||||
L = GTP | |||||||
Pr(III) | 3.046379 | 0.8665 | 0.4574 | 0.8226 | −7.583 | 1.8484 | 9.5285 |
| (3.046379) | (0.6606) | (0.6704) | (0.8226) |
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Pr(III): L | 3.111372 | 1.0156 | 0.5161 | 0.8627 | −98.86 | 2.0885 | 9.9804 |
| (3.111372) | (0.7235) | (0.7187) | (0.8627) |
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Pr(III): L: Ca(II) | 3.263881 | 1.2437 | 0.5295 | 0.8695 | −98.16 | 2.3661 | 10.8392 |
| (3.263881) | 90.7788) | (0.7748) | (0.8695) |
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5. Solvent: CH3OH + CH3CN | |||||||
L = GTP | |||||||
Pr(III) | 2.80359 | 0.6412 | 0.3699 | 0.6799 | −28.15 | 1.4295 | 8.8345 |
| (2.80359) | (0.5186) | (0.5004) | (0.6799) |
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Pr(III): L | 2.846376 | 0.9439 | 0.4358 | 0.7733 | −39.08 | 2.2492 | 9.7052 |
| (2.846376) | (0.6909) | (0.6895) | (0.7733) |
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Pr(III): L: Ca(II) | 3.033962 | 1.0425 | 0.4411 | 0.7975 | −10.03 | 2.2546 | 9.7632 |
| (3.033962) | (0.7529) | (0.714) | (0.7975) |
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