System

³H₄ → ¹D₂

³H₄ → ³P₀

³H₄ → ³P₁

³H₄ → ³P₂

T₂

T₃

T₄

P_obs

(P_cal)

P_obs

(P_cal)

P_obs

(P_cal)

P_obs

(P_cal)

1. Solvent: CH₃CN

L = Guanosine

Pr(III)

2.443861

0.8924

0.4264

0.7052

−2.439

1.8207

7.5293

(2.443861)

(0.6627)

(0.6526)

(0.7052)

Pr(III): L

2.884613

0.8955

0.4329

0.831

−2.833

1.8823

9.0123

(2.884613)

(0.6725)

(0.653)

(0.831)

Pr(III): L: Ca(II)

2.900472

0.9035

0.4473

0.8849

−14.32

1.914

9.0552

(2.900472)

(0.6839)

(0.6644)

(0.8849)

2. Solvent: CH₃OH

L = Guanosine

Pr(III)

2.669057

0.7966

0.4078

0.7868

1.4653

1.663

8.3098

(2.669057)

(0.6053)

(0.5961)

(0.7868)

Pr(III): L

2.991033

0.8058

0.4382

0.7966

−17.57

1.7181

9.3518

(2.991033)

(0.6254)

(0.6159)

(0.7966)

Pr(III): L: Ca(II)

2.997821

0.8469

0.4396

0.8058

−23.69

1.7541

9.4903

(2.997821)

(0.6329)

(0.4854)

(0.8058)

3. Solvent: Dioxane

L = Guanosine

Pr(III)

2.689602

0.7523

0.4066

0.7949

2.1498

1.6006

8.3953

(2.689602)

(0.5826)

(0.5737)

(0.7949)

Pr(III): L

3.330865

0.8596

0.4869

0.9848

2.6164

1.86

10.43

(3.330865)

(0.677)

(0.6667)

(0.9848)

Pr(III): L: Ca(II)

3.343981

0.8609

0.4963

0.9885

-49.61

1.8783

10.566

(3.343981)

(0.6872)

(0.6774)

(0.9885)

4. Solvent: DMF

L = Guanosine

Pr(III)

3.066379

0.8865

0.4874

0.8626

−7.603

1.8984

9.5585

(3.066379)

(0.6906)

(0.6804)

(0.8626)

Pr(III): L

3.125784

1.0515

0.5306

0.866

−17.88

2.1858

10.6778

(3.125784)

(0.795)

(0.7834)

(0.866)

Pr(III): L: Ca(II)

3.673293

1.6665

0.5312

0.8729

16.251

2.6434

11.7374

(3.673293)

(0.8077)

(0.789)

(0.8729)

5. Solvent: CH₃OH + CH₃CN

L = Guanosine

Pr(III)

2.82359

0.6812

0.3899

0.6999

−28.18

1.4795

8.8645

(2.89359)

(0.5386)

(0.5304)

(0.6999)

Pr(III): L

3.180095

1.0815

0.4516

0.8795

−11.54

2.1153

9.8644

(3.180095)

(0.77)

(0.7583)

(0.8795)

Pr(III): L: Ca(II)

3.195112

1.086

0.4525

0.8885

−15.02

2.173

10.968

(3.195112)

(0.7834)

(0.779)

(0.8885)