C^c

CM3

CM7

E

R3

R7

C

CM3

CM7

E

R3

R7

1^st Vintage

2^ns Vintage

pH

3.55 ± 0.04^a

3.51 ± 0.07^ad

3.47 ± 0.19^a

3.41 ± 0.01^a

3.40 ± 0.03^a

3.45 ± 0.10^a

3.96 ± 0.02^b

3.82 ± 0.03^a

3.98 ± 0.00^b

3.81 ± 0.00^a

3.83 ± 0.04^a

3.81 ± 0.05^a

T.A^b.

5.45 ± 0.12^a

5.76 ± 0.05^a

6.02 ± 0.05^a

6.07 ± 0.01^a

5.88 ± 0.18^a

6.90 ± 0.61^b

4.46 ± 0.09^a

4.50 ± 0.00^a

4.32 ± 0.03^a

4.98 ± 0.01^b

4.43 ± 0.01^a

4.89 ± 0.21^b

V.A.

0.59 ± 0.02^b

0.60 ± 0.01^b

0.59 ± 0.14^ab

0.60 ± 0.01^b

0.60 ± 0.01^b

0.50 ± 0.00^a

0.40 ± 0.00^b

0.30 ± 0.02^a

0.27 ± 0.06^a

0.40 ± 0.04^b

0.34 ± 0.01^ab

0.30 ± 0.02^a

ºAlc

13.5 ± 0.05^b

13.4 ± 0.33^b

13.6 ± 0.37^b

12.6 ± 0.00^a

13.5 ± 0.49^b

14.0 ± 0.47^b

12.9 ± 0.01^b

12.7 ± 0.05^ab

13.5 ± 0.06^c

13.0 ± 0.25^b

12.5 ± 0.06^a

13.0± 0.30^b

TP

1186 ± 54^a

1161 ± 60^a

1301 ± 113^c

1377 ± 97^c

1205 ± 29^ab

1293 ± 95^bc

1719 ± 22^b

1388 ± 91^a

1701 ± 14^b

1849 ± 59^c

1341 ± 76^a

1683 ± 43^b

Acy

540 ± 15^bc

500 ± 51^a

512 ± 43^ab

507 ± 16^ab

538 ± 14^bc

571 ± 3 ^c

544 ± 3^c

469 ± 29^a

540 ± 5^c

515 ± 8^b

501 ± 15^b

536 ± 25^bc

Cat

226 ± 30^a

273 ± 22^b

314 ± 26^c

330 ± 18^c

245 ± 15^a

333 ± 3^c

496 ± 4^b

358 ± 52^a

572 ± 22^c

651 ± 116^d

317 ± 38^a

540 ± 27^c

Tar-Est

174 ± 3^cd

156 ± 15^ab

170 ± 17^bc

188 ± 11^de

151 ± 8^a

191 ± 16^e

242 ± 1^c

194 ± 5^a

234 ± 6^c

222 ± 3^b

190 ± 14^a

215 ± 7^b

Flav

128 ± 2^ab

115 ± 11^a

135 ± 21^bc

143 ± 10^cd

126 ± 4^ab

155 ± 17^d

156 ± 1^a

163 ± 4^ab

187 ± 8^c

187 ± 4^c

158 ± 14^a

167 ± 5^b

Tan

830 ± 20^a

910 ± 15^b

1050 ± 3^c

1090 ± 3^c

940 ± 5^b

1.02 ± 0.01^c

1430 ± 1^c

1160 ± 16^b

1600 ± 2^d

1610 ± 12^d

990 ± 8^a

1410 ± 6^c

Acy Ac

29.3 ± 0.7^cd

25.7 ± 1.2^b

21.5 ± 0.9^a

27.1 ± 0.5^bc

25.8 ± 0.1^b

30.5 ± 5.5^e

41.7 ± 1.4^ab

46.0 ± 0.7^c

42.9 ± 0.5^b

40.7 ± 0.9^a

42.6 ± 1.7^b

47.1 ± 0.8^c

AcyCin

76.4 ± 6.2^c

58.0 ± 3.4^a

65.8 ± 8.8^ab

72.1 ± 5.9^bc

77.8 ± 12.1^c

79.1 ± 0.1^c

21.5 ± 0.7^a

32.8 ± 1.4^d

24.0 ± 1.4^c

23.2 ± 0.0^bc

21.9 ± 1.1^ab

33.3 ± 2.0^d

AcyGls

417 ± 4^ab

423 ± 7^ab

413 ± 16^ab

408 ± 9^a

431 ± 23^b

509 ± 28^c

320 ± 9^bc

326 ± 1^c

321 ± 4^bc

293 ± 3^a

314 ± 17^b

350 ± 6^d

AcyPir

0.57 ± 0.09^b

0.42 ± 0.01^a

0.44 ± 0.03^a

0.66 ± 0.10^b

0.46 ± 0.16^a

0.40 ± 0.00^a

1.33 ± 0.01^a

1.35 ± 0.31^a

1.15 ± 0.04^a

1.38 ± 0.33^a

1.68 ± 0.02^b

1.61 ± 0.13^b

Total Acy

523 ± 3^bc

507 ± 7^ab

500 ± 24^a

508 ± 7^ab

537 ± 23^c

618 ± 28^d

396 ± 12^b

415 ± 1^c

400 ± 7^b

367 ± 5^a

386 ± 26^b

443 ± 9^d

CI

13.0 ± 0.5^a

11.8 ± 0.6^a

12.8 ± 1.8^a

15.0 ± 0.9^b

11.8 ± 1.6^a

15.6 ± 0.6^b

11.4 ± 0.7^b

10.2 ± 0.5^a

11.2 ± 0.1^b

12.8 ± 0.6^c

9.69 ± 1.07^a

11.1 ± 0.4^b

To

0.52 ± 0.01^ab

0.52 ± 0.00^b

0.52 ± 0.01^ab

0.48 ± 0.03^a

0.48 ± 0.02^a

0.53 ± 0.08^b

0.79 ± 0.04^d

0.73 ± 0.03^c

0.69 ± 0.01^a

0.71 ± 0.01^b

0.75 ± 0.01^c

0.68 ± 0.02^a

%Yellow

30.6 ± 0.1^ab

30.8 ± 0.2^b

30.6 ± 0.2^ab

29.2 ± 0.8^a

29.1 ± 0.6^a

31.3 ± 3.0^b

34.4 ± 0.0^a

37.1 ± 0.7^c

35.8 ± 0.1^b

36.0 ± 0.1^b

37.5 ± 0.1^d

35.4 ± 0.2^ab

% Blue

10.2 ± 0.2^d

10.1 ± 0.1^d

8.90 ± 0.08^cd

9.50 ± 0.70^bc

9.30 ± 0.39^ab

9.10 ± 0.10^a

13.5 ± 0.0^b

12.2 ± 0.6^a

12.5 ± 0.6^a

13.2 ± 0.6^b

12.1 ± 0.3^a

11.9 ± 0.9^a

% Red

59.3 ± 0.3^a

59.2 ± 0.1^a

59.5 ± 0.1^a

61.3 ± 1.5^b

59.6 ± 2.9^a

61.6 ± 1.0^b

48.2 ± 0.1^a

50.7 ± 1.2^b

51.7 ± 0.7^c

50.8 ± 0.7^bc

50.3 ± 0.2^b

52.7 ± 1.0^d

ABTS

18.0 ± 1.0^a

17.7 ± 3.0^a

20.3 ± 2.1^ab

20.8 ± 3.4^b

18.3 ± 1.7^ab

17.7 ± 1.3^a

22.9 ± 0.2^d

17.7 ± 0.8^a

21.4 ± 0.5^c

26.1 ± 2.2^e

19.1 ± 0.9^b

22.9 ± 0.5^d

FRAP

37.0 ± 0.5^b

36.5 ± 1.4^b

41.6 ± 1.1^d

39.1 ± 0.7^c

33.7 ± 1.2^a

36.6 ± 0.1^b

34.3 ± 0.3^c

29.0 ± 1.1^a

32.0 ± 1.2^bc

39.2 ± 4.8^d

30.3 ± 1.7^ab

37.0 ± 1.6^d

HRSA

47.4 ± 1.4^b

41.0 ± 1.8^a

43.2 ± 8.7^ab

46.1 ± 3.7^b

46.2 ± 4.0^b

46.8 ± 0.3^b

47.9 ± 3.1^b

45.4 ± 2.9^b

45.2 ± 4.5^b

37.3 ± 1.3^a

47.7 ± 2.3^b

44.7 ± 4.0^b