Sample | Mnz3_p1 | Mnz3_p11 | Mnz3_p15 | Mnz3_p20 | Mnz3_p24 | Mnz3_p30 | Mnz3_p33 | Mnz3_p40 | Mnz3_p48 | Mnz3_p55 |
Comment | Rim | Intermediate | Core | Intermediate | Core | |||||
SiO2 (wt%) | 3.58 | 3.80 | 3.36 | 3.03 | 2.79 | 2.84 | 2.83 | 3.29 | 4.16 | 4.01 |
FeO | 0.02 | 0.01 | 0.02 | 0.04 | 0.15 | 0.07 | 0.01 | 0.00 | 0.00 | 0.00 |
MgO | 0.78 | 0.82 | 0.80 | 0.84 | 0.94 | 0.93 | 0.88 | 0.91 | 0.74 | 0.75 |
CaO | 23.10 | 22.66 | 23.29 | 23.74 | 24.27 | 24.20 | 24.20 | 23.69 | 22.38 | 22.46 |
P2O5 | 1.15 | 1.19 | 1.01 | 1.07 | 0.96 | 0.85 | 0.95 | 1.02 | 1.30 | 1.17 |
PbO | 18.45 | 19.35 | 17.37 | 16.06 | 15.38 | 15.68 | 15.59 | 17.41 | 20.41 | 20.10 |
ThO2 | 0.32 | 0.24 | 0.25 | 0.19 | 0.21 | 0.14 | 0.25 | 0.22 | 0.34 | 0.31 |
UO2 | 0.84 | 0.91 | 0.81 | 0.91 | 0.78 | 0.75 | 0.81 | 0.86 | 0.84 | 0.85 |
Y2O3 | 9.99 | 9.48 | 10.13 | 10.02 | 10.45 | 10.41 | 10.33 | 9.85 | 9.45 | 9.32 |
La2O3 | 26.19 | 25.73 | 26.65 | 27.11 | 27.73 | 27.39 | 27.55 | 26.40 | 25.40 | 25.50 |
Ce2O3 | 2.85 | 2.84 | 2.90 | 3.19 | 2.94 | 2.93 | 3.07 | 2.90 | 2.82 | 2.82 |
Pr2O3 | 9.30 | 9.26 | 9.42 | 9.77 | 9.47 | 9.49 | 9.70 | 9.71 | 9.35 | 9.10 |
Nd2O3 | 1.47 | 1.43 | 1.39 | 1.53 | 1.50 | 1.44 | 1.57 | 1.41 | 1.45 | 1.43 |
Sm2O3 | 0.92 | 0.95 | 0.95 | 1.11 | 0.90 | 0.99 | 0.95 | 0.99 | 1.03 | 1.01 |
Gd2O3 | 0.21 | 0.19 | 0.23 | 0.19 | 0.25 | 0.20 | 0.23 | 0.24 | 0.21 | 0.23 |
Dy2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.03 | 0.00 | 0.00 |
Ho2O3 | 0.04 | 0.10 | 0.07 | 0.09 | 0.07 | 0.05 | 0.00 | 0.00 | 0.09 | 0.13 |
Er2O3 | 0.03 | 0.00 | 0.00 | 0.02 | 0.04 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 |
Yb2O3 | 0.03 | 0.00 | 0.00 | 0.04 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.05 |
F | 0.55 | 0.50 | 0.54 | 0.55 | 0.51 | 0.53 | 0.55 | 0.54 | 0.51 | 0.59 |
F = O | −0.23 | −0.21 | −0.23 | −0.23 | −0.22 | −0.22 | −0.23 | −0.23 | −0.21 | −0.25 |
Cl | 0.02 | 0.03 | 0.02 | 0.04 | 0.02 | 0.03 | 0.03 | 0.03 | 0.01 | 0.01 |
Cl = O | −0.01 | −0.01 | −0.01 | −0.01 | −0.01 | −0.01 | −0.01 | −0.01 | 0.00 | 0.00 |
Total | 99.61 | 99.26 | 98.98 | 99.30 | 99.13 | 98.70 | 99.27 | 99.26 | 100.27 | 99.59 |
Structural formulae based on 16 oxygen atoms | ||||||||||
Si (apfu.) | 1.230 | 1.297 | 1.170 | 1.069 | 0.989 | 1.009 | 1.003 | 1.142 | 1.393 | 1.354 |
Fe | 0.005 | 0.001 | 0.005 | 0.013 | 0.044 | 0.019 | 0.002 | 0.001 | 0.000 | 0.000 |
Ca | 0.287 | 0.300 | 0.300 | 0.317 | 0.356 | 0.352 | 0.334 | 0.337 | 0.266 | 0.273 |
P | 3.357 | 3.277 | 3.437 | 3.541 | 3.646 | 3.639 | 3.630 | 3.481 | 3.173 | 3.207 |
Pb | 0.106 | 0.109 | 0.095 | 0.101 | 0.092 | 0.082 | 0.090 | 0.096 | 0.117 | 0.107 |
Th | 1.441 | 1.504 | 1.378 | 1.288 | 1.242 | 1.267 | 1.257 | 1.375 | 1.555 | 1.543 |
U | 0.024 | 0.018 | 0.019 | 0.015 | 0.016 | 0.011 | 0.020 | 0.017 | 0.025 | 0.023 |