[(Pip)4nCu4X4Y2] n, X, Y | Temp. ˚C | k2a,b | DH≠c | DS≠d | Ke | DH˚c | DS˚d |
2, Cl, O* | 18 | 0.170 | 16.5 ± 0.5 | −116 ± 3 | 3440 | 13.4 ± 0.5 | −86 ± 3 |
| 30 | 0.260 |
|
| 3800 |
|
|
| 36 | 0.440 |
|
| 8760 |
|
|
| 42 | 0.770 |
|
| 9100 |
|
|
1, Cl, CO3 | 25 | 0.015 | 11.2 ± 0.5 | −30 ± 3 | 62 | 12.0 ± 0.5 | −10 ± 3 |
| 32 | 0.018 |
|
| 78 |
|
|
| 38 | 0.040 |
|
| 104 |
|
|
| 50 | 0.062 |
|
| 380 |
|
|
1, Br, CO3 | 22 | 0.192 | 11.0 ± 0.5 | −26 ± 3 | 430 | 4.0 ± 0.5 | −32 ± 3 |
| 28 | 0.263 |
|
| 540 |
|
|
| 36 | 0.510 |
|
| 560 |
|
|
| 45 | 0.770 |
|
| 1040 |
|
|
2, Cl, CO3 | 25 | 0.067 | 12.0 ± 0.5 | −23 ± 3 | 120 | 3.0 ± 0.5 | −39 ± 3 |
| 38 | 0.167 |
|
| 176 |
|
|
| 45 | 0.213 |
|
| 196 |
|
|
| 50 | 0.263 |
|
| 250 |
|
|
2, Br, CO3 | 20 | 0.210 | 12.0 ± 0.5 | −22 ± 3 | 323 | 0.4 ± 0.5 | −46 ± 3 |
| 25 | 0.310 |
|
| 333 |
|
|
| 40 | 0.870 |
|
| 357 |
|
|
| 50 | 1.72 |
|
| 375 |
|
|