Complex 1 C25H19F12N4O5Ni(1) Ni(hfac)2(IM-o-QN) | |||
Bond | Length/Å | Bond | Length/Å |
Ni1-O4 | 2.009(3) | N3-C9 | 1.292(5) |
Ni1-O5 | 2.023(4) | O4-C21 | 1.257(5) |
Ni1-O2 | 2.029(3) | O3-C18 | 1.237(6) |
Ni1-O3 | 2.030(3) | N4-O1 | 1.263(5) |
Ni1-N3 | 2.056(4) | N4-C9 | 1.384(5) |
Ni1-N1 | 2.166(4) | N1-C8 | 1.339(5) |
N1-C6 | 1.365(5) | O5-C23 | 1.250(6) |
O2-C16 | 1.256(5) | C5-N2 | 1.352(6) |
Bond | Angle/˚ | Bond | Angle/˚ |
O4-Ni1-O5 | 90.57(14) | N3-Ni1-N1 | 78.61(14) |
O4-Ni1-O2 | 89.28(13) | C23-O5-Ni1 | 124.3(4) |
O5-Ni1-O2 | 84.46(14) | N3-C9-N4 | 113.3(4) |
O4-Ni1-O3 | 177.55(13) | N3-C9-C8 | 121.1(4) |
O5-Ni1-O3 | 89.19(14) | N4-C9-C8 | 125.5(4) |
O2-Ni1-O3 | 88.27(13) | C8-N1-C6 | 116.4(4) |
O4-Ni1-N3 | 94.57(14) | C8-N1-Ni1 | 111.7(3) |
O5-Ni1-N3 | 96.44(15) | C6-N1-Ni1 | 131.8(3) |
O2-Ni1-N3 | 176.03(13) | C16-O2-Ni1 | 123.3(3) |
O3-Ni1-N3 | 87.87(13) | C9-N3-C11 | 109.1(4) |
O4-Ni1-N1 | 92.98(13) | C9-N3-Ni1 | 112.9(3) |
O5-Ni1-N1 | 174.12(13) | C11-N3-Ni1 | 136.7(3) |
O2-Ni1-N1 | 100.26(14) | C21-O4-Ni1 | 123.4(3) |
O3-Ni1-N1 | 87.46(13) | C18-O3-Ni1 | 123.5(3) |
Complex 2 C25H19F12N4O5Zn(2) Zn(hfac)2(IM-o-QN) | |||
Bond | Length/Å | Bond | Length/Å |
O3-C16 | 1.252(4) | N3-C9 | 1.280(3) |
O3-Zn1 | 2.062(2) | N3-C11 | 1.490(3) |
Zn1-N3 | 2.079(2) | O5-C21 | 1.248(4) |
Zn1-O5 | 2.088(2) | O4-C18 | 1.245(4) |
Zn1-O6 | 2.098(2) | O6-C23 | 1.238(4) |
Zn1-O4 | 2.107(2) | N1-C8 | 1.315(4) |
Zn1-N1 | 2.258(2) | N1-C6 | 1.375(3) |
N4-C10 | 1.487(4) | O2-N4 | 1.260(3) |
N2-C5 | 1.348(5) | N4-C9 | 1.381(4) |
Bond | Angle/˚ | Bond | Angle/˚ |
C16-O3-Zn1 | 122.3(2) | O2-N4-C9 | 126.5(2) |
O3-Zn1-N3 | 104.00(9) | O2-N4-C10 | 123.4(3) |
O3-Zn1-O5 | 84.50(10) | C9-N4-C10 | 109.7(2) |