Compound

lnm

u (cm−1)

(emaxmolar−1∙L∙cm−1)

Electronic transition

Suggested structure

(HL)

276

36,231

1885

p ® p*

-

346

28,901

614

n ® p*

362

27,624

500

n ® p*

[Mn(HL)2(N3)2(H2O)2]∙H2O

297

33,670

2370

Intra-ligand

Oh

345

28,986

2042

Intra-ligand

359

27,855

1324

Intra-ligand

475

21,053

208

6A1g ® 4T2g(G)

638

15,674

41

6A1g ® 4T1g(G)

794

12,594

7

6A1g ® 4Eg(D)

[Co(HL)2(N3)2]∙2H2O

286

34,965

2304

Intra-ligand

oh

345

28,986

2034

Intra-ligand

362

27,624

1228

Intra-ligand

650

15,387

13

4T1g ® 4A2g

879

11,377

4

4T1g ® 4T2g

[Ni(HL)2(N3)2]∙3H2O

281

35,587

2218

Intra-ligand

Oh

347

28,818

1152

Intra-ligand

365

27,397

842

Intra-ligand

426

23,474

323

3A1g ® 3T2g(P)

792

15,942

10

3A1g ® 3T1g

879

11,377

2

3A1g ® 3T2g

[Zn(HL)2(N3)2]∙3H2O

286

34,965

2278

Intra-ligand

Oh

345

28,986

1489

Intra-ligand

354

28,249

962

Intra-ligand

[Cd(HL)2(N3)2]∙2H2O

286

34,965

2276

Intra-ligand

Oh

345

28,986

1485

Intra-ligand

354

28,249

960

Intra-ligand

[Hg(HL)2(N3)2]∙3H2O

284

35,211

2274

Intra-ligand

Oh

345

28,986

2085

Intra-ligand

354

28,249

1266

Intra-ligand