Sample | Un-altered precursor rock (lapillituff) | Argillic alteration facies (lapillituff) | Advance argillic alteration facies (lapillituff) | Silicic alteration facies (lapillituff) | ||||||||
CUA-1 | CUA-2 | CA-1 | CA-2 | CA-3 | CA-4 | CAD-1 | CAD-2 | CAD-3 | CAD-4 | CSI-1 | CSI-2 | |
Major element (wt.%) | ||||||||||||
SiO2 | 55.54 | 59.7 | 78.21 | 74.38 | 46.39 | 72.3 | 90.74 | 77.94 | 74.76 | 68.22 | 94.55 | 90.48 |
Al2O3 | 16.64 | 16.19 | 12.3 | 13.14 | 16.99 | 17.69 | 5.56 | 13.56 | 14.58 | 16.85 | 0.67 | 2.79 |
Fe2O3 | 8.68 | 7.96 | 1.63 | 0.78 | 9.83 | 0.52 | 1.25 | 0.96 | 1.93 | 4.33 | 2.25 | 1.75 |
CaO | 7.58 | 6.57 | 0.09 | 2.24 | 7.82 | 0.12 | 0.07 | 0.09 | 0.13 | 0.12 | 0.12 | 1.25 |
Na2O | 2.85 | 3.3 | 1.69 | 0.88 | 2.69 | 0.08 | 0.02 | 0.02 | 0.04 | 0.03 | 0.03 | 0.44 |
K2O | 1.2 | 1.3 | 1.66 | 2.13 | 0.59 | 1.23 | 0.03 | 0.04 | 0.09 | 0.07 | 0.03 | 0.2 |
MgO | 4.23 | 2.65 | 0.19 | 0.22 | 5.2 | 0.11 | 0.02 | 0.01 | 0.03 | 0.03 | 0.02 | 0.58 |
MnO | 0.166 | 0.151 | 0.006 | 0.024 | 0.191 | 0.007 | 0.004 | 0.004 | 0.004 | 0.006 | 0.012 | 0.028 |
TiO2 | 0.837 | 0.815 | 0.283 | 0.302 | 0.884 | 0.619 | 0.496 | 0.615 | 0.626 | 0.438 | 0.421 | 0.43 |
P2O5 | 0.16 | 0.15 | <0.01 | 0.01 | 0.15 | 0.13 | 0.1 | 0.18 | 0.22 | 0.18 | 0.07 | 0.03 |
L.O.I. | 1.21 | 1.4 | 4.23 | 5.83 | 8.88 | 6.13 | 2.48 | 5.5 | 6.72 | 9.12 | 1.59 | 0.56 |
Total | 99.08 | 100.2 | 100.3 | 99.94 | 99.6 | 98.92 | 100.8 | 98.91 | 99.12 | 99.38 | 99.75 | 98.54 |
Trace element (ppm) | ||||||||||||
S | 0.035 | 0.023 | 1.1 | 0.057 | 0.025 | 0.012 | 0.064 | 0.067 | 1.41 | 3.59 | 1.1 | 0.096 |
V | 206 | 161 | 14 | 21 | 244 | 137 | 34 | 107 | 86 | 105 | 24 | 38 |
Sc | 25 | 25 | 11 | 12 | 32 | 12 | 4 | 11 | 7 | 8 | 5 | 7 |
Be | 1 | 1 | bdl | bdl | bdl | 1 | 1 | bdl | bdl | bdl | bdl | bdl |
Cr | 30 | bdl | bdl | bdl | 200 | bdl | bdl | bdl | bdl | bdl | bdl | bdl |
Co | 24 | 18 | 2 | 1 | 30 | bdl | bdl | bdl | 4 | 8 | bdl | 4 |
Ni | 22 | 13 | bdl | bdl | 42 | bdl | bdl | bdl | 2 | 3 | bdl | 5 |
Cu | 78 | 49 | 5 | 3 | 22 | 19 | 22 | 12 | 18 | 62 | 58 | 28 |
Zn | 66 | 76 | 47 | 18 | 66 | 9 | 5 | 4 | 15 | 31 | 4 | 14 |
Rb | 52 | 54 | 40 | 59 | 15 | 45 | bdl | bdl | bdl | 2 | bdl | 9 |
Sr | 251 | 208 | 52 | 110 | 677 | 296 | 333 | 816 | 955 | 469 | 60 | 55 |
Y | 24 | 29 | 27 | 36 | 16 | 19 | 5 | 6 | 8 | 8 | 3 | 5 |
Nb | 3 | 4 | 1 | 2 | 1 | 3 | 3 | 2 | 3 | 2 | 2 | 2 |
Ba | 146 | 211 | 137 | 220 | 113 | 143 | 101 | 238 | 411 | 363 | 119 | 38 |
W | <1 | <1 | 1 | bdl | bdl | bdl | 3 | 15 | 4 | 2 | 3 | bdl |
Pb | 5 | 8 | bdl | 6 | bdl | 22 | 638 | 910 | 220 | 222 | 225 | 109 |
Th | 4.8 | 4.8 | 2.2 | 2.2 | 1.1 | 6.9 | 10 | 8.4 | 4.8 | 6.6 | 6.6 | 4.7 |
U | 1.2 | 1 | 0.6 | 0.5 | 0.2 | 2 | 1.8 | 3.4 | 1.2 | 2.1 | 1.9 | 1.5 |
Zr | 106 | 113 | 121 | 118 | 42 | 86 | 86 | 72 | 109 | 65 | 86 | 78 |