Kinetic Parameter

Description

Reference

Rate constant for superoxide production

[1]

MichaelisMenten constant for superoxide production

[1]

kFe3

“Rate constant for the conversion of superoxide to oxygen with simultaneous reduction of Fe3+ to Fe2+

[2]

kH2O2

Rate constant for the production of hydrogen peroxide and oxygen from superoxide and H+ (non-enzymatic)

[2]

kSOD

Rate constant for superoxide dismutase producing hydrogen peroxide from superoxide

[3]

KmH2O2

MichaelisMenten constant for catalase induced conversion of H2O2 to H2O

[4]

kcata

Rate constant for catalase induced conversion of H2O2 to H2O

[4]

kFe1

Fenton reaction rate constant (hydrogen peroxide forming hydroxyl radical and anion with simultaneous conversion of Fe2+ to Fe3+)

[2]

kinitLR

Rate constant for lipid peroxidation reaction by hydroxyl radicals, forming lipid radicals

[5]

kLPO

Rate constant for the oxidation of lipid radicals

[5]

kLR1

Rate constant for the formation of L* and LOOH from LH and LOO*

[5]

kLRFe1

Rate constant for Fe2+ induced formation of LO* from LOOH

[6]

kLRFe2

Rate constant for Fe3+ induced formation of LOO* from LOOH

[6]

kfrLOO

Rate constant for LOO* fragmentation to alkane radical and aldehyde product

[7]

kFe4

Rate constant for OH* induced formation of HO2* from H2O2

[2]

kFe5

Rate constant for Fe3+ induced formation of HO* from H2O2

[2]

kFe8

Rate constant for H2O2 formation from HO2*

[2]

kFe9

Rate constant for the conversion of HO2* and H2O2 to H2O and OH*

[2]

kFe6

Rate constant of Fe2+induced conversion of OH* to OH

[2]

kFe7

Rate constant for the conversion of OH* and HO2* to H2O and O2

[2]

kdH2O

Dissociation rate of H2O to H+ and OH−

[8]

KH2O

Association rate of H+ and OH− to H2O

[8]

kAPX

Rate constant for APX induced conversion of Ascorbate to MDA

[3]

KAPX

MichaelisMenten constant for APX induced conversion of ASC to MDA

[3]

KAPXH

MichaelisMenten constant for APX induced conversion of H2O2 to H2O

[3]

k_ASCH2O2

Rate constant for ASC and H2O2

[3]

k_ASCO2

Rate constant for superoxide reacting with ascorbate

[3]

kMDAR

Rate constant for molecular MDAR activity

[3]

KMDARM

MichaelisMenten constant of MDAR for MDA

[3]

KMDARN

MichaelisMenten constant of MDAR for NADPH

[3]

k_MDAMDA

Apparent rate constant of MDA

[3]

kDAR

Rate constant for molecular DAR activity

[3]

KDAR

MichaelisMenten constant of DAR for DHA

[3]