Sample | Fe-shale | Shale | Arkose | Fe-sandstone |
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Ref. code | BB2 | BB3 | BB4 | EDDd | MTR5 | MTR4 | TJC1 | TJC2 | TJC4 | MTFb | MTR1 | TJC3 | TJC5 | BB5 | BB1 | PAAS | UCC |
Ba | 194.00 | 146.50 | 387.00 | 1505.00 | 1220.00 | 138.50 | 1020.00 | 1090.00 | 1870.00 | 1345.00 | 534.00 | 1265.00 | 1110.00 | 193.50 | 104.00 | 650.00 | 550.00 |
Cr | 390.00 | 600.00 | 120.00 | 20.00 | 70.00 | 110.00 | 90.00 | 60.00 | 80.00 | 40.00 | <10 | 40.00 | 20.00 | 160.00 | 60.00 | 110.00 | 83.00 |
Zr | 371.00 | 362.00 | 348.00 | 110.00 | 567.00 | 242.00 | 442.00 | 336.00 | 1680.00 | 721.00 | 110.00 | 196.00 | 171.00 | 371.00 | 531.00 | 210.00 | 190.00 |
Cs | 0.17 | 0.38 | 2.94 | 1.56 | 7.23 | 5.90 | 6.83 | 4.62 | 4.86 | 3.97 | 1.07 | 2.05 | 0.91.00 | 0.73 | 1.09 | 5.16 | 4.60 |
Th | 7.71 | 8.74 | 16.55 | 10.60 | 30.20 | 26.30 | 25.10 | 1.15 | 50.50 | 32.30 | 6.04 | 9.91 | 8.83 | 9.15 | 15.10 | 14.60 | 10.70 |
U | 2.06 | 3.51 | 7.22 | 2.89 | 3.24 | 4.00 | 3.09 | 3.69 | 5.96 | 3.75 | 1.02 | 2.14 | 1.9.00 | 2.74 | 2.01 | 3.10 | 2.80 |
V | 460.00 | 581.00 | 115.00 | 39.00 | 68.00 | 75.00 | 82.00 | 71.00 | 81.00 | 41.00 | 11.00 | 47.00 | 19.00 | 108.00 | 91.00 | 150.00 | 107.00 |
Hf | 8.80 | 8.80 | 8.40 | 3.30 | 16.60 | 7.00 | 11.50 | 9.30 | 44.50 | 20.00 | 3.40 | 4.80 | 4.70 | 8.60 | 13.40 | 5.00 | 5.80 |
Nb | 86.20 | 80.40 | 45.50 | 11.10 | 20.90 | 21.50 | 22.70 | 16.60 | 26.20 | 16.10 | 3.80 | 8.50 | 5.20 | 29.50 | 35.60 | 19.00 | 12.00 |
Sr | 138.00 | 74.60 | 109.50 | 341.00 | 170.00 | 296.00 | 186.50 | 250.00 | 310.00 | 183.00 | 154.50 | 259.00 | 216.00 | 43.50 | 79.70 | 200.00 | 350.00 |
Y | 28.10 | 33.50 | 86.30 | 8.80 | 33.10 | 116.00 | 35.40 | 22.50 | 67.70 | 26.40 | 12.70 | 21.00 | 7.30 | 10.90 | 19.60 | 27.00 | 22.00 |
Ta | 5.60 | 5.00 | 3.10 | 0.80 | 1.50 | 1.60 | 1.60 | 1.30 | 2.20 | 1.30 | 0.40 | 0.60 | 0.40 | 1.90 | 2.40 | 1.28 | 1.00 |
Ga | 39.50 | 36.40 | 27.50 | 17.00 | 25.30 | 35.40 | 24.40 | 19.40 | 25.40 | 19.30 | 11.20 | 14.90 | 9.30 | 13.10 | 19.00 | 20.00 | 17.00 |
Rb | 3.50 | 3.20 | 57.00 | 158.50 | 256.00 | 134.50 | 233.00 | 191.50 | 190.50 | 213.00 | 66.10 | 152.00 | 114.50 | 24.10 | 12.10 | 160.00 | 112.00 |
Ni | 311.00 | 179.00 | 53.00 | 33.00 | 29.00 | 39.00 | 33.00 | 31.00 | 22.00 | 16.00 | 14.00 | 12.00 | 6.00 | 21.00 | 25.00 | 55.00 | 44.00 |
Co | 26.00 | 23.00 | 27.00 | 21.00 | 9.00 | 10.00 | 8.00 | 10.00 | 5.00 | 5.00 | 32.00 | 7.00 | 1.00 | 4.00 | 2.00 | 23.00 | 17.00 |
Cu | 78.00 | 89.00 | 34.00 | 18.00 | 3.00 | 13.00 | <1 | 25.00 | 5.00 | 2.00 | 6.00 | 7.00 | 1.00 | 14.00 | 9.00 | 50.00 | 25.00 |
Sc | 37.00 | 37.00 | 16.00 | 3.00 | 9.00 | 12.00 | 11.00 | 9.00 | 10.00 | 6.00 | 1.00 | 6.00 | 2.00 | 9.00 | 9.00 | 16.00 | 13.60 |
Pb | <2 | <2 | 22.00 | 51.00 | 26.00 | 16.00 | 25.00 | 25.00 | 48.00 | 22.00 | 31.00 | 25.00 | 20.00 | 8.00 | 13.00 | 20.00 | 17.00 |
Zn | 187.00 | 120.00 | 57.00 | 8.00 | 54.00 | 67.00 | 63.00 | 40.00 | 37.00 | 29.00 | 5.00 | 28.00 | <2 | 23.00 | 22.00 | 85.00 | 71.00 |
W | 2.00 | 2.00 | 1.00 | 1.00 | 1.00 | 2.00 | 1.00 | 1.00 | 2.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 2.00 | - | - |
Sn | 3.00 | 3.00 | 3.00 | 2.00 | 5.00 | 5.00 | 4.00 | 3.00 | 4.00 | 3.00 | 1.00 | 1.00 | 1.00 | 1.00 | 3.00 | - | - |
Li | 10.00 | 10.00 | 30.00 | <10 | - | 10.00 | <10 | <10 | 10.00 | <10 | <10 | 10.00 | 10.00 | 10.00 | 10.00 | - | - |
Ti | <10 | <10 | <10 | <10 | 10.00 | <10 | <10 | <10 | <10 | <10 | <10 | <10 | <10 | <10 | <10 | - | - |
Zr/Hf | 42.16 | 41.14 | 41.43 | 33.33 | 34.16 | 34.57 | 38.43 | 36.13 | 37.75 | 36.05 | 32.35 | 40.83 | 36.38 | 43.14 | 39.63 | 42.00 | 32.80 |
Cr/Th | 50.58 | 68.65 | 7.25 | 1.89 | 2.32 | 4.18 | 3.59 | 52.17 | 1.58 | 1.24 | - | 4.04 | 2.27 | 17.49 | 3.97 | 7.53 | 7.76 |
Cr/Ni | 1.25 | 3.35 | 2.26 | 0.61 | 2.41 | 2.82 | 2.73 | 1.94 | 3.64 | 2.50 | - | 3.33 | 3.33 | 7.62 | 2.40 | 2.00 | 1.89 |
V/Cr | 1.18 | 0.97 | 0.96 | 1.95 | 0.97 | 0.68 | 0.91 | 1.18 | 1.01 | 1.03 | - | 1.18 | 0.95 | 0.68 | 1.52 | 1.36 | 1.29 |
Th/Cr | 0.02 | 0.01 | 0.14 | 0.53 | 0.43 | 0.24 | 0.28 | 0.02 | 0.63 | 0.81 | - | 0.25 | 0.44 | 0.06 | 0.25 | 0.13 | 0.13 |
Th/U | 3.74 | 2.49 | 2.29 | 3.67 | 9.32 | 6.58 | 8.12 | 0.31 | 8.47 | 8.61 | 5.92 | 4.63 | 8.10 | 3.34 | 7.51 | 4.71 | 3.82 |
Th/Co | 0.30 | 0.38 | 0.61 | 0.50 | 3.36 | 2.63 | 3.14 | 0.12 | 10.10 | 6.46 | 0.19 | 1.42 | 8.83 | 2.29 | 7.55 | 0.63 | 0.63 |
Th/Sc | 0.21 | 0.24 | 1.03 | 3.53 | 3.36 | 2.19 | 2.28 | 0.13 | 5.05 | 5.38 | 6.04 | 1.65 | 4.42 | 1.02 | 1.68 | 0.91 | 0.79 |
U/Th | 0.27 | 0.40 | 0.44 | 0.27 | 0.11 | 0.15 | 0.12 | 3.21 | 0.12 | 0.12 | 0.17 | 0.22 | 0.12 | 0.30 | 0.13 | 0.21 | 0.26 |
Ni/Co | 11.96 | 7.78 | 1.96 | 1.57 | 3.22 | 3.90 | 4.13 | 3.10 | 4.40 | 3.20 | 0.44 | 1.71 | 6.00 | 5.25 | 12.50 | 1.10 | 2.59 |
Cu/Zn | 0.42 | 0.74 | 0.60 | 2.25 | 0.06 | 0.19 | 0.01 | 0.63 | 0.13 | 0.07 | 1.20 | 0.25 | 0.50 | 0.61 | 0.41 | 0.58 | 0.35 |
Y/Ni | 0.09 | 0.19 | 1.63 | 0.27 | 1.14 | 2.97 | 1.07 | 0.73 | 3.08 | 1.65 | 0.91 | 1.75 | 1.22 | 0.52 | 0.78 | 0.49 | 0.50 |
Co/Th | 3.37 | 2.63 | 1.63 | 1.98 | 0.30 | 0.38 | 0.32 | 8.70 | 0.10 | 0.15 | 5.30 | 0.71 | 0.11 | 0.44 | 0.13 | 1.58 | 1.59 |
Zr/Cr | 0.95 | 0.60 | 2.90 | 5.50 | 8.10 | 2.20 | 4.91 | 5.60 | 21.00 | 1.03 | - | 4.90 | 8.55 | 2.32 | 8.85 | 1.91 | 2.29 |
Zr/Sc | 10.03 | 9.78 | 21.75 | 36.67 | 63.00 | 20.17 | 40.18 | 37.33 | 168.00 | 120.17 | 110.00 | 32.67 | 85.50 | 41.22 | 59.00 | 13.13 | 13.97 |
Cr/V | 0.85 | 1.03 | 1.04 | 0.51 | 1.03 | 1.47 | 1.10 | 0.85 | 0.99 | 0.98 | - | 0.85 | 1.05 | 1.48 | 0.66 | 0.73 | 0.78 |
Cr/Zr | 1.05 | 1.65 | 0.34 | 0.18 | 0.12 | 0.45 | 0.20 | 0.18 | 0.05 | 0.06 | - | 0.20 | 0.12 | 0.43 | 0.11 | 0.52 | 0.43 |