Symbol

Band Positions (cm⁻¹)

assignment

Dq/

(cm⁻¹) (b)

10 Dq

(cm⁻¹)

Molar Conductivity

S∙mol⁻¹∙m² (DMSO)

µ_eff B.M (geom)

C₈ Co(II)

n₁ 7092 (cal.)

n₂ 15,723

n₃ 18,519

⁴T1g ® ⁴T_2g(F)

⁴T_1g ® ⁴ A₂g(F)

⁴T_1g ® ⁴ T_1g(P)

1.0

813 (0.837)

8130

0.0107

4.4 (Oh)

C₇ Ni(II)

n₁ 11,442

n₂ 15,924

n₃ 29,812(cal.)

³A₂g ® ³T₂g

³A₂g ® ³T₁g(F)

³A₂g ® ³T₁g(P)

2.6

514 (0.5)

13,364

0.0077

2.9 (Oh)

C₉ Cu(II)

n₁ 16,234

²Eg ® ²T₂g

-

-

-

0.0066

1.66 (Oh)

C₁₀ Cd(II)

n₁ 38,314

n₂ 33,557

IL p ® p^*

IL p ® p^*

-

-

0.0054

Diam. (Oh)

C₁₁ Pd(II)

n₁ 17,762

n₂ 22,075

¹A₁g ® ¹A₂g

¹A₁g ® ¹B₁g

-

-

0.011

Diam. (Sq.p)

C₁₂ Pt(IV)

n₁ 38,023

n₂ 21,053

IL p ® p^*

¹A₁g ® ³T₁g

0.0699

Diam. (Oh)