104 (mol∙dm−3) | 103 [S] (mol∙dm−3) | 102 [H+] (mol∙dm−3) | I (mol∙dm−3) | 105 kobs (s−1) | |||||||
Perchloric acid | Sulfuric acid | ||||||||||
Fl | Fl-Cl | Fl-Br | Fl-I | Fl | Fl-Cl | Fl-Br | Fl-I | ||||
1.0 | 5.0 | 0.2 | 0.5 | 166.2 | 101.2 | 113.9 | 129.2 | 139.3 | 86.2 | 98.7 | 121.0 |
2.0 | 5.0 | 0.2 | 0.5 | 165.7 | 98.3 | 117.4 | 135.6 | 135.7 | 87.9 | 97.8 | 115.2 |
4.0 | 5.0 | 0.2 | 0.5 | 168.1 | 99.7 | 116.9 | 133.1 | 137.2 | 88.0 | 99.3 | 117.6 |
6.0 | 5.0 | 0.2 | 0.5 | 172.1 | 100.7 | 115.2 | 132.2 | 141.1 | 85.9 | 103.2 | 118.1 |
8.0 | 5.0 | 0.2 | 0.5 | 169.3 | 97.3 | 118.2 | 134.1 | 133.2 | 89.2 | 98.2 | 116.2 |
4.0 | 1.0 | 0.2 | 0.5 | 79.8 | 39.2 | 48.4 | 59.7 | 50.1 | 32.8 | 36.3 | 41.7 |
4.0 | 3.0 | 0.2 | 0.5 | 127.3 | 74.1 | 85.3 | 97.2 | 96.9 | 62.3 | 73.1 | 87.2 |
4.0 | 5.0 | 0.2 | 0.5 | 168.1 | 99.7 | 116.9 | 133.1 | 137.2 | 88.0 | 99.3 | 117.6 |
4.0 | 7.0 | 0.2 | 0.5 | 201.0 | 120.2 | 139.9 | 161.0 | 175.9 | 108.7 | 125 | 145.0 |
4.0 | 9.0 | 0.2 | 0.5 | 232.4 | 141.5 | 166.2 | 189.8 | 204.9 | 128.2 | 152 | 175.4 |
4.0 | 5.0 | 0.1 | 0.5 | 105.3 | 63.1 | 70.3 | 81.9 | 81.6 | 48.5 | 55.8 | 68.9 |
4.0 | 5.0 | 0.2 | 0.5 | 139.9 | 84.7 | 95.3 | 111.2 | 112.0 | 71.8 | 83.3 | 95.2 |
4.0 | 5.0 | 0.3 | 0.5 | 168.1 | 99.7 | 116.9 | 133.1 | 137.2 | 88.0 | 99.3 | 117.6 |
4.0 | 5.0 | 0.4 | 0.5 | 195.3 | 115.0 | 134.9 | 158.0 | 159.3 | 102.1 | 115.8 | 134.3 |
4.0 | 5.0 | 0.5 | 0.5 | 216.0 | 124.9 | 148.0 | 181.0 | 185.0 | 113.9 | 132.2 | 155.0 |
4.0 | 5.0 | 0.2 | 0.5 | 168.1 | 99.7 | 116.9 | 133.1 | 137.2 | 88.0 | 99.3 | 117.6 |
4.0 | 5.0 | 0.2 | 0.6 | 169.7 | 98.3 | 119.4 | 135.6 | 135.7 | 87.9 | 101.2 | 115.2 |
4.0 | 5.0 | 0.2 | 0.7 | 171.2 | 102.7 | 116.9 | 134.4 | 139.2 | 91.2 | 99.3 | 121.6 |
4.0 | 5.0 | 0.2 | 0.8 | 172.1 | 105.7 | 121.2 | 137.2 | 141.1 | 85.9 | 103.2 | 118.1 |
4.0 | 5.0 | 0.2 | 0.9 | 167.3 | 97.4 | 118.1 | 134.1 | 139.2 | 87.2 | 104.3 | 122.2 |