Compound

rHo

fHo

MHo

DHo

rHo(g)

D(M-S)

MnBr2(s)

−384.9a

205.9a

CoBr2(s)

−220.9a

183a

NiBr2(s)

−212.1a

170a

CuBr2(s)

−141.8a

182.4a

ZnBr2(s)

−328.65a

159.7a

CdBr2(s)

−316.2b

151.2c

TMTU(S)

−38.3 ± 2.3d

82.36 ± 0.20d

[MnBr2(TMTU)2](s)

−1.91 ± 2.35

−463.4 ± 5.5

−228.4 ± 17.6

−372.5 ± 3.1

166.63 ± 2.38

−228.4 ± 17.6

114.2 ± 8.8

[CoBr2(TMTU)3](s)

−61.70 ± 2.07

−396.6 ± 7.5

133 ± 16

−492 ± 2

308.78 ± 2.16

−359 ± 16

120 ± 5

[NiBr2(TMTU)2](s)

−11.68 ± 2.87

−300.4 ± 5.6

126.2 ± 15.1

−346.5 ± 3.1

176.40 ± 2.90

−220.3 ± 15.4

110.2 ± 7.7

[CuBr2(TMTU)2](s)

−40.90 ± 1.85

−259.3 ± 3.6

132.4 ± 15.9

−388 ± 2

205.62 ± 1.89

−256 ± 16

128 ± 8

[ZnBr2(TMTU)2](s)

−41.83 ± 1.28

−447.1 ± 5.2

121.0 ± 14.5

−366.3 ± 2.4

206.55 ± 1.34

−245.3 ± 14.7

122.7 ± 7.4

[CdBr2(TMTU)2](s)

−19.00 ± 3.10

−131.8 ± 5.6

116.8 ± 14.0

−334.9 ± 3.3

187.72 ± 3.13

−218.1 ± 14.4

109.1 ± 7.2