Compound* | Apparent MP/K | Mass loss/% | TG temperature range/K | Species lost | DSC peak temperature | ∆Ho/kJ∙mol−1 | |
Calcd. | Obs. | ||||||
[MnBr2(L2] | 423 - 25 | 1.93 | 1.84 | 325 - 353 | −0.07L | 346 | 1.53 |
|
| 38.65 | 38.21 | 353 - 487 | −1.41L | 421 | 35.99 |
|
| 14.63 | 16.19 | 487 - 564 | −0.53L |
|
|
|
| 28.34 | 28.39 | 884 - 962 | −1.7Br |
|
|
|
|
| 15.00a |
|
|
|
|
[FeBr2(L)0.75] | 438 - 41 | 9.00 | 8.67 | 375 - 494 | −0.21L | 349 | −5.66 |
|
| 13.50 | 12.72 | 494 - 531 | −0.32L | 413 | 2.33 |
|
| 26.26 | 26.08 | 531 - 700 | −0.22L - 0.68Br | 469 | 1.33 |
|
| 19.29 | 19.69 | 700 - 858 | −0.76Br | 510 | 0.32 |
|
| 4.06 | 4.07 | 858 - 915 | −0.16Br |
|
|
|
|
| 28.77a |
|
|
|
|
[CoBr2(L3] | 355 - 57 | 25.79 | 25.53 | 353 - 389 | −1.20L | 340 | 30.36 |
|
| 26.86 | 26.61 | 389 - 538 | −1.25L | 385 | 9.77 |
|
| 15.71 | 16.03 | 538 - 564 | −0.55L - 0.3Br |
|
|
|
| 18.17 | 18.67 | 564 - 861 | −1.4Br |
|
|
|
|
| 13.16a |
|
|
|
|
[NiBr2(L2] | 433 - 35 | 54.76 | 55.24 | 428 - 505 | −2L | 393 | 1.09 |
|
| 28.12 | 27.44 | 505 - 890 | −1.7Br | 427 | 27.48 |
|
|
| 17.32a |
|
| 442 | 21.49 |
[CuBr2(L)2] | 353 - 55 | 70.60 | 68.07 | 398 - 484 | −2L - Br | 352 | 38.19 |
|
| 26.80 | 26.76 | 484 - 838 | −Br - 0.8Cu | 441 | 2.62 |
|
|
| 5.17a |
|
|
|
|
[ZnBr2(L)2] | 433 - 35 | 35.10 | 35.09 | 434 - 591 | −1.3L | 430 | 38.51 |
|
| 13.54 | 13.24 | 591 - 615 | −0.5L |
|
|
|
| 46.05 | 46.26 | 615 - 760 | −0.2L - 2Br - 0.6Zn |
|
|
|
| 1.34 | 0.83 | 760 - 942 | −0.1Zn |
|
|
|
|
| 4.58a |
|
|
|
|
[CdBr2(L)2] | 442 - 44 | 36.96 | 36.62 | 412 - 570 | −1.5L | 434 | 42.08 |
|
| 12.32 | 13.15 | 570 - 580 | −0.5L |
|
|
|
| 49.67 | 49.12 | 784 - 838 | −2Br - 0.95Cd |
|
|
|
|
| 1.11a |
|
|
|
|