Entry | Brønsted acid (mol%) | Cobalt salt | Time/h | Yield/% | |
2 | 1 | ||||
1 | PhSO3H(10) | - | 2 | 4.9 | 53.1 |
2 | CH3SO3H(10) | - | 2 | 0.0 | 47.9 |
3 | CF3SO3H(10) | - | 2 | 5.7 | 53.5 |
4 | H3PO4(10) | - | 2 | 0.0 | 58.8 |
5 | H2SO4(10) | - | 2 | 0.0 | 56.5 |
6 | H2SO4(20) | - | 2 | 3.3 | 56.1 |
7 |
| CoCl2 | 2 | 0.0 | 83.4 |
8 | - | Co(NO3)2∙6H2O | 2 | 7.8 | 72.6 |
9 | - | Co(ClO4)2∙6H2O | 2 | 8.2 | 40.1 |
10 | - | Co(BF4)2∙6H2O | 2 | 10.3 | 32.0 |
11 | PhSO3H(10) | CoCl2 | 2 | 47.7 | 40.3 |
12 | PhSO3H(10) | Co(NO3)2∙6H2O | 2 | 22.5 | 29.4 |
13 | PhSO3H(10) | Co(ClO4)2∙6H2O | 2 | 30.5 | 26.9 |
14 | PhSO3H(10) | Co(BF4)2∙6H2O | 2 | 64.9 | 26.8 |
15 | PhSO3H(10) | Co(BF4)2∙6H2O | 4 | 88.3 | 5.5 |
16 | H3PO4(10) | Co(BF4)2∙6H2O | 2 | 26.8 | 31.6 |
17 | CF3SO3H(10) | Co(BF4)2∙6H2O | 2 | 27.9 | 20.0 |
18 | CH3SO3H(10) | Co(BF4)2∙6H2O | 2 | 45.0 | 15.2 |
19 | H2SO4(10) | Co(BF4)2∙6H2O | 2 | 12.5 | 48.3 |
20 | H2SO4(20) | Co(BF4)2∙6H2O | 2 | 56.7 | 22.5 |
21 | H2SO4(10) | Co(BF4)2∙6H2O | 24 | 69.3 | 20.2 |
22 | H2SO4(20) | Co(BF4)2∙6H2O | 24 | 86.3 | 6.6 |