|
| 1 | 7 | 5 | ||||||
| 13C | 1H | J (Hz) | 13C | 1H | J (Hz) | 13C | 1H | J (Hz) | |
| 2 | 164.0 |
|
| 164.0 |
|
| 164.3 |
|
|
| 3 | 103.0 | 6.74 | s | 103.4 | 6.98 | s | 103.1 | 6.74 | s |
| 4 | 181.9 |
|
| 182.0 |
|
| 181.8 |
|
|
| 5 | 160.4 |
|
| 160.3 |
|
| 161.6 |
|
|
| 6 | 102.2 | 6.57 | d (2.1) | 102.3 | 6.56 | d (2.1) | 99.30 | 6.44 | d (2.1) |
| 7 | 159.3 |
|
| 159.6 |
|
| 162.5 |
|
|
| 8 | 97.7 | 6.98 | d (2.0) | 97.9 | 7.04 | d (2.1) | 94.6 | 6.76 | d (2.2) |
| 9 | 156.1 |
|
| 156.3 |
|
| 156.8 |
|
|
| 10 | 105.4 |
|
| 105.7 |
|
| 105.3 |
|
|
| 1' | 120.3 |
|
| 121.4 |
|
| 121.3 |
|
|
| 2' | 120.3 | 7.93 | d (2.3) | 110.2 | 7.58 | d (2.1) | 113.5 | 7.42 | d (2.2) |
| 3' | 141.3 |
|
| 147.7 |
|
| 145.9 |
|
|
| 4' | 153.7 |
|
| 150.6 |
|
| 146.9 |
|
|
| 5' | 117.3 | 6.99 | d (8.3) | 115.6 | 6.94 | d (8.3) | 115.9 | 6.90 | d (8.4) |
| 6' | 123.4 | 7.71 | dd (8.7, 2.3) | 120.4 | 7.60 | dd (8.3, 2.2) | 119.0 | 7.45 | dd (8.4, 2.2) |
| OCH3 |
|
|
| 56.0 | 3.89 |
|
|
|
|
| Sugar |
|
|
|
|
|
|
|
|
|
| 1'' |
|
|
|
|
|
| 101.3 | 5.12 | d (7.6) |
| 2'' |
|
|
|
|
|
| 74.6 | 3.59 | m |
| 3'' |
|
|
|
|
|
| 77.7 | 3.58 | m |
| 4'' |
|
|
|
|
|
| 71.1 | 3.47 | dd (8.7, 9.4) |
| 5'' |
|
|
|
|
|
| 75.5 | 3.86 | m |
| 6A'' |
|
|
|
|
|
| 65.3 | 4.61 | dd (2.1, 11.7) |
| 6B'' |
|
|
|
|
|
| 65.3 | 4.41 | dd (6.6, 11.7) |
| Acyl |
|
|
|
|
|
|
|
|
|
| 1''' |
|
|
|
|
|
| 168.5 |
|
|
| 2A''' |
|
|
|
|
|
| 52.7 | 3.71 | s |
| 2B''' |
|
|
|
|
|
| 52.7 | 3.81 | s |
| 3''' |
|
|
|
|
|
| 169.2 |
|
|