Run

Monomer structure

Polymer structure

Mnb

Mw/Mn

Yield of PS (%)c

1

Ph2SiCl2

(Ph2Si)n (6)

1000

1.1

72

2

PhSiCl3

(PhSi)n (7)

1380

1.4

76

3

n-HexMeSiCl2

(n − HexMeSi)n

-

-

-

4

HexMeSiCl2 + MePhSiCl2

(n − HexMeSi)m − (MePhSi)n (8)

6200

1.5

36

5

MePhSiCl2 + Me3SiCl

TMS − (MePhSi)n − TMS (9)

950

1.1

92