Compound

Ir spectral data

Position of absorption band (cm−1)

1H NMR

Chemical shift (δ) in ppm

13C NMR

Chemical shift (δ)

in ppm

Mass spectral data

FE1

3630 (Ar-OH), 1695 (C=Ostr., ester), 3010 (C-H str., aromatic),

1596 (C=C skeletal str., phenyl),

1699 (C=C str., alkene), 1123 (C-O str. Ester), 2860 (C-H str., Ar-OCH3)

5.00 Ar-OH(s.1H), 3.91-OCH3 (s, 1H),

3.78-ArOCH3 (s, 3H),

7.630 (d, 1H, C1 of acrylate, j = 1.2 Hz),

6.90 (d, 1H, C2 of acrylate, j = 8 Hz)

6.37 Ar-H (d, 1H, j = 1.6 Hz)

6.925 Ar-H (d, 1H, j= 1.6 Hz)

144.9(C1),

151.3(C2),

112.0(C3),

143.7(C1’)

118.1(C2’)

166.5(C3’)

56.2(C4’)

Molecular ion peak at 209

FE2

3600 (Ar-OH), 1685 (C=Ostr., ester), 3004 (C-H str., aromatic),

1592 (C=C skeletal str., phenyl),

1689 (C=C str., alkene), 1080 (C-O str. Ester), 2842

(C-H str., Ar-OCH3)

5.27 Ar-OH (s.1H), 3.88 OCH3 (s, 1H),

3.88-ArOCH3 (s, 3H),

7.010 (d, 1H, C1 of acrylate, j = 4 Hz),

6.890 (s, 1H, C2 of acrylate)

6.256Ar-H (d, 1H j = Hz)

6.890 Ar-H (d, 1H j = 0.8 Hz)

144.9(C1),

151.3(C2),

112.0(C3),

145.7(C1’)

116.1(C2’)

166.5(C3’)

61.4(C4’)

14.2(C5’)

56.2(C4’)

Molecular ion peak at 223

FE3

3620 (Ar-OH), 1675 (C=Ostr., ester), 3006 (C-H str., aromatic),

1589 (C=C skeletal str., phenyl),

1685 (C=C str., alkene), 1095 (C-O str. Ester), 2946

(C-H str., Ar-OCH3)

710.94 ( long chain band)

5.890 (1H s Ar-OH), 3.924 (1H , s, OCH3),

3.88-ArOCH3 (s, 3H),

7.059 (d, 1H, C1 of acrylate, j = 3.6 Hz),

6.275 (s, 1H, C2 of acrylate)

6.904 Ar-H (d, 1H j = 1.2 Hz)

7.036 Ar-H (d, 1H j = 4.4 Hz)

1.012 CH3 of propyl chain, (m3H)

1.682 CH2of propyl chain, (m, 2H)

4.174 CH2of propyl chain, (m , 2H)

144.9(C1),

152.3(C2),

116.3(C3),

56.2(C4’)

148.7(C1’)

118.1(C2’)

169.5(C3’)

67.6(C4’)

22.2(C5’)

10.2(C6’)

Molecular ion peak at 237

FE4

3625 (Ar-OH), 1679 (C=O str., ester), 3010 (C-H str., aromatic),

1565 (C=C skeletal str., phenyl),

1695 (C=C str., alkene), 1099 (C-O str. Ester), 2846

(C-H str., Ar-OCH3)

750.94 (long chain band)

5.813 (1H s Ar-OH),

3.907 (1H , s, OCH3),

3.907-ArOCH3 (s, 3H),

7.044 (d, 1H, C1ofacrylate, j = 16 Hz),

7.570 (s, 1H, C2 of acrylate)

6.246 Ar-H (d, 1H j = 2.4 Hz)

6.896 Ar-H (d, 1H j = 8 Hz)

1.312 CH3 of propyl chain, (m, 6H)

5.084 - 5.162 CH2of propyl chain, (m)

147.9(C1),

155.3(C2),

119.3(C3),

56.2(C4’)

152.7(C1’)

122.1(C2’)

168.5(C3’)

69.6(C5’)

24.2(C6’.C7’)

Molecular ion peak at 237

FE5

3629 (Ar-OH), 1685 (C=Ostr., ester), 3003 (C-H str., aromatic),

1575 (C=C skeletal str., phenyl),

1687 (C=C str., alkene), 1095 (C-O str. Ester), 2946

(C-H str., Ar-OCH3)

718.94 (long chain band)

5.890 (1H s Ar-OH),

3.923-ArOCH3 (s, 3H),

7.056 (d, 1H, C1of acrylate, j = 2 Hz),

7.584 (d, 1H, C2 of acrylate, j = 16 Hz)

6.307Ar-H (d, 1H j = 16 Hz)

6.922 Ar-H (d, 1H j = 6 Hz)

0.98 CH3 of butyl chain, (m 3H)

1.465 - 1.409 (m) CH2 of butyl chain,

1.720 - 1.625 (m) CH2 of butyl chain,

147.9(C1),

155.3(C2),

119.3(C3),

152.7(C1’)

122.1(C2’)

168.5(C3’)

56.2(C4’)

65.1(C5’)

31.3(C6’).

19.0(C7’)

13.8(C8’)

Molecular ion peak at 251

FE6

3625 (Ar-OH), 1689 (C=Ostr., ester), 3009 (C-H str., aromatic),

1565 (C=C skeletal str., phenyl),

1697 (C=C str., alkene), 1085 (C-O str. Ester), 2956

(C-H str., Ar-OCH3)

613.94 (long chain band)

5.180 (1H s Ar-OH),

3.943-ArOCH3 (s, 3H),

7.086 (d, 1H, C1of acrylate, j = 9.6 Hz),

7.594 (d, 1H, C2 of acrylate, j = 12 Hz)

6.207Ar-H (d, 1H j = 5.6 Hz)

6.944 Ar-H (d, 1H j = 3.2 Hz)

4.11 CH of butyl chain, (d, 2H j = 20.8 Hz)

1.012 (d, 6 H, j = 39.2 Hz CH3of butyl chain,

2.400 - 2.475 (m, 2H) CH of iso butyl chain.

149.9(C1),

150.3(C2),

117.3(C3),

155.7(C1’)

120.1(C2’)

167.5(C3’)

74.9(C4’)

27.8(C5’).

19.4(C6’)

19.4(C7’)

Molecular ion peak at 251