Quaternary volcanism | ||||||||||||||||||
Sample | 6 | 17 | 25 | 26 | 27 | 28 | 14 | A | 16 | 19 | 29 | 18 | DK12 | DK11 | DK5 | DK10 | DK4 | DK9 |
SiO2 | 48.23 | 47.54 | 46.91 | 47.90 | 48.24 | 47.97 | 50.27 | 49.35 | 51.30 | 50.65 | 50.51 | 47.13 | 48.42 | 51.72 | 46.90 | 49.84 | 48.20 | 51.75 |
Al2O3 | 14.80 | 15.04 | 14.60 | 14.87 | 14.69 | 14.66 | 17.27 | 14.90 | 14.72 | 14.69 | 15.44 | 14.82 | 15.18 | 15.21 | 14.92 | 15.60 | 15.08 | 14.66 |
Fe2O3 | 10.41 | 10.61 | 9.81 | 10.32 | 10.96 | 10.82 | 12.08 | 11.30 | 10.44 | 9.71 | 10.63 | 10.26 | 10.91 | 10.30 | 10.46 | 10.71 | 10.89 | 10.91 |
MnO | 0.13 | 0.14 | 0.13 | 0.13 | 0.14 | 0.14 | 0.11 | 0.15 | 0.14 | 0.10 | 0.12 | 0.14 | 0.12 | 0.12 | 0.12 | 0.13 | 0.13 | 0.13 |
MgO | 7.88 | 7.99 | 7.83 | 7.40 | 8.41 | 8.20 | 3.52 | 7.04 | 7.33 | 7.39 | 5.56 | 7.98 | 7.18 | 7.24 | 8.21 | 7.26 | 7.76 | 7.01 |
CaO | 7.33 | 8.00 | 9.42 | 8.75 | 8.59 | 7.91 | 6.83 | 8.88 | 9.01 | 8.50 | 9.07 | 9.07 | 7.84 | 8.96 | 8.32 | 9.36 | 8.36 | 8.73 |
Na2O | 4.06 | 4.79 | 4.30 | 3.89 | 3.66 | 4.51 | 3.78 | 3.72 | 3.94 | 3.78 | 4.05 | 4.16 | 5.05 | 4.01 | 4.20 | 3.84 | 4.74 | 3.95 |
K2O | 1.97 | 1.46 | 1.52 | 1.43 | 1.24 | 1.68 | 0.59 | 1.04 | 0.69 | 0.76 | 0.47 | 1.45 | 1.62 | 0.61 | 1.43 | 0.70 | 1.51 | 0.63 |
TiO2 | 2.18 | 2.13 | 1.89 | 1.90 | 1.81 | 2.13 | 1.61 | 1.70 | 1.52 | 1.49 | 1.55 | 1.88 | 2.12 | 1.35 | 2.00 | 1.43 | 1.86 | 1.54 |
P2O5 | 0.69 | 0.60 | 0.56 | 0.59 | 0.50 | 0.55 | 0.30 | 0.47 | 0.33 | 0.34 | 0.33 | 0.58 | 0.53 | 0.36 | 0.60 | 0.34 | 0.61 | 0.40 |
PF | 2.66 | 1.07 | 1.84 | 1.97 | 1.19 | 0.88 | 3.63 | 1.16 | -0.04 | 1.86 | 1.85 | 1.69 | 0.58 | nd | 2.48 | 0.57 | 0.51 | 0.03 |
Total | 100 | 99.36 | 98.80 | 99.13 | 99.41 | 99.43 | 99.99 | 99.70 | 99.39 | 99.28 | 99.56 | 99.15 | 99.55 | 99.88 | 99.64 | 99.78 | 99.65 | 99.74 |
NaO/K2O | 2.06 | 3.29 | 2.83 | 2.72 | 2.95 | 2.69 | 6.37 | 3.58 | 5.68 | 4.97 | 8.70 | 2.87 | 3.12 | 6.57 | 2.94 | 5.49 | 3.14 | 6.27 |
Ne' | 2.93 | 8.01 | 8.33 | 2.62 | 1.29 | 8.82 | 0 | 0 | 0 | 0 | 0 | 6.52 | 8.52 | 0 | 5.72 | 0 | 7.76 | 0 |
Co | 54.9 | 56.9 | 68.3 | 84.9 | 68.8 | 67.5 | 54.7 | 57.1 | 70.5 | 47.2 | 60.6 | 50.8 | 55 | 63 | 51 | 65 | 60 | 60 |
Cr | 238 | 253 | 225 | 239 | 262 | 307 | 274 | 257 | 237 | 215 | 242 | 215 | 246 | 261 | 236 | 244 | 257 | 35 |
Cs | 0.66 | 1.66 | 0.36 | 0.43 | 0.20 | 0.58 | | 0.23 | | | | 0.41 | nd | nd | nd | nd | nd | nd |
Hf | 4.34 | 4.08 | 3.45 | 3.59 | 3.14 | 3.81 | 2.55 | 2.88 | 2.15 | 2.30 | 2.29 | 3.73 | nd | nd | nd | nd | nd | nd |
Nb | 66.5 | 58.2 | 52.8 | 53.3 | 46.1 | 55.8 | 30.1 | 41.2 | 30.6 | 31.1 | 32.1 | 51.5 | 56 | 31 | 59 | 27 | 57 | 33 |
Ni | 226 | 231 | 215 | 212 | 237 | 268 | 151 | 218 | 136 | 125 | 116 | 190 | 229 | 146 | 199 | 197 | 227 | 140 |
Rb | 57.4 | 17.2 | 40.9 | 38 | 28.2 | 45 | 12.3 | 25.4 | 15.3 | 16.9 | 4.47 | 37.4 | 39 | 17 | 35 | 19 | 44 | 17 |
Sr | 858 | 749 | 772 | 741 | 674 | 714 | 442 | 595 | 466 | 433 | 487 | 742 | 710 | 496 | 768 | 491 | 758 | 451 |
Ta | 5.01 | 4.54 | 3.84 | 3.92 | 3.20 | 4.19 | 1.76 | 2.71 | 1.89 | 1.80 | 1.86 | 3.80 | nd | nd | nd | nd | nd | nd |
Th | 4.56 | 5.23 | 4.07 | 4.17 | 3.51 | 3.79 | 2.88 | 2.87 | 2.77 | 3.18 | 3.16 | 4.60 | nd | nd | nd | nd | nd | nd |
U | 0.63 | 1.19 | 0.79 | 0.94 | 0.72 | 0.86 | 0.67 | 0.73 | 0.48 | 0.82 | 0.67 | 1.09 | nd | nd | nd | nd | nd | nd |
V | 114 | 141 | 126 | 131 | 136 | 137 | 97.2 | 138 | 133 | 122 | 131 | 132 | 145 | 134 | 146 | 47 | 151 | 143 |
Y | 18.9 | 20.2 | 19.8 | 20.6 | 20.4 | 19.7 | 23.6 | 19.9 | 16.6 | 16.9 | 19.1 | 20.3 | 19 | 17 | 20 | 42 | 21 | 19 |
Zr | 181 | 161 | 148 | 149 | 132 | 154 | 86.1 | 113 | 79.4 | 84.4 | 87.3 | 148 | 143 | 71 | 146 | 74 | 156 | 79 |
La | 37.71 | 34.88 | 32.84 | 33.44 | 30.07 | 30.80 | 36.95 | 27.79 | 24.36 | 26.26 | 26.19 | 33.88 | 28.88 | 24.46 | 33.80 | 36.91 | 33.68 | 25.65 |
Ce | 68.64 | 64.48 | 61.09 | 61.81 | 55.47 | 56.23 | 52.74 | 51.44 | 43.70 | 47.24 | 46.39 | 63.01 | 51.03 | 49.13 | 63.23 | 38.26 | 67.13 | 48.37 |
Pr | 7.92 | 7.45 | 7.02 | 7.15 | 6.55 | 6.53 | 7.84 | 6.00 | 4.79 | 5.18 | 5.25 | 7.30 | nd | nd | nd | nd | nd | nd |
Nd | 32.13 | 30.07 | 28.05 | 28.85 | 26.13 | 26.89 | 31.49 | 24.51 | 18.55 | 20.02 | 20.67 | 29.40 | 26.79 | 18.56 | 28.39 | 26.53 | 28.39 | 19.49 |
Sm | 7.14 | 6.65 | 6.26 | 6.38 | 5.82 | 6.37 | 7.17 | 5.37 | 4.09 | 4.38 | 4.66 | 6.41 | 6.98 | 4.69 | 6.64 | 6.62 | 6.89 | 4.67 |
Eu | 2.48 | 2.33 | 2.18 | 2.22 | 2.06 | 2.21 | 2.53 | 1.89 | 1.56 | 1.62 | 1.67 | 2.28 | 2.25 | 1.64 | 2.26 | 2.22 | 2.27 | 1.65 |
Gd | 6.52 | 6.21 | 5.64 | 5.78 | 5.36 | 5.69 | 7.08 | 5.27 | 4.26 | 4.49 | 4.60 | 6.08 | 6.58 | 4.78 | 6.20 | 7.93 | 6.41 | 4.75 |
Tb | 0.87 | 0.87 | 0.79 | 0.82 | 0.78 | 0.82 | 1.01 | 0.76 | 0.62 | 0.65 | 0.69 | 0.85 | nd | nd | nd | nd | nd | nd |
Dy | 4.31 | 4.57 | 4.20 | 4.37 | 4.18 | 4.30 | 5.37 | 4.03 | 3.36 | 3.58 | 3.83 | 4.49 | 4.35 | 3.43 | 4.39 | 5.54 | 4.43 | 3.75 |
Ho | 0.68 | 0.75 | 0.71 | 0.74 | 0.70 | 0.71 | 0.90 | 0.70 | 0.59 | 0.62 | 0.68 | 0.75 | nd | nd | nd | nd | nd | nd |
Er | 1.51 | 1.81 | 1.71 | 1.75 | 1.67 | 1.68 | 2.17 | 1.76 | 1.45 | 1.57 | 1.67 | 1.82 | 1.72 | 1.53 | 1.70 | 2.54 | 1.77 | 1.61 |
Tm | 0.18 | 0.23 | 0.22 | 0.23 | 0.22 | 0.22 | 0.27 | 0.22 | 0.19 | 0.21 | 0.23 | 0.23 | nd | nd | nd | nd | nd | nd |
Yb | 1.01 | 1.36 | 1.27 | 1.34 | 1.29 | 1.20 | 1.65 | 1.34 | 1.18 | 1.25 | 1.33 | 1.42 | 1.11 | 1.12 | 1.25 | 1.61 | 1.30 | 1.28 |
Lu | 0.13 | 0.18 | 0.17 | 0.19 | 0.18 | 0.17 | 0.24 | 0.19 | 0.16 | 0.17 | 0.19 | 0.20 | 0.17 | 0.22 | 0.21 | 0.29 | 0.23 | 0.23 |