Wave number (cm1)

Assignments

3330

asymmetric N-H stretching

3082

asymmetric C-H stretching

2782

symmetric C-H stretching vibration of methyl group

1966

overtones and combinations

1638

C=C stretching due to the aromatic ring

1549

asymmetric stretching of NO2 group

1494

COO stretching

1442

-CH3 asymmetric bending

1369

-CH3 symmetric bending

1315

symmetric stretching of NO2 group

1270

C-O stretching

1233

N-H…S hydrogen bonding

1158

C-H bending

1079

Ρ (NH2)

1051

C-N stretching

1022

C-H bending (in plane)

963

C-H bending

936

C-H deformation

907

C-NO2 stretching

894

C-C-N symmetric stretching

827

NO2 scissoring

794

C-H bending (out of plane)

751

NO2 wagging

698

C-H bending (out of plane)

546

NO2 rocking

522

NO2 scissoring

506

δ(N-C-S)