Lengths (Å) | |||
Pt(1)-O(5) | 1.986(11) | W(1)-O(3) | 1.787(12) |
Pt(1)-O(10) | 2.013(10) | W(2)-O(5) | 1.790(11) |
Pt(2)-O(3) | 1.986(11) | W(5)-O(11) | 1.780(10) |
Pt(2)-O(11) | 2.005(11) | W(6)-O(10) | 1.774(10) |
Average | 1.998 | Average | 1.783 |
Pt(1)-N(1) | 2.023(16) | W(1)-O(4) | 1.937(10) |
Pt(1)-N(2) | 2.018(13) | W(2)-O(4) | 1.895(10) |
Pt(2)-N(3) | 2.013(13) | W(5)-O(19) | 1.957(10) |
Pt(2)-N(4) | 2.049(13) | W(6)-O(19) | 1.949(10) |
Average | 2.026 | Average | 1.935 |
|
| Pt(1)×××Pt(2) | 3.455 |
Angles (˚) | |||
Pt(1)-O(5)-W(2) | 151.5(6) | Pt(2)-O(3)-W(1) | 157.0(6) |
Pt(1)-O(10)-W(6) | 146.9(7) | Pt(2)-O(11)-W(5) | 146.6(7) |
Average | 149.2 | Average | 151.8 |
O(5)-Pt(1)-O(10) | 91.5(4) | O(3)-Pt(2)-O(11) | 92.5(4) |
O(5)-Pt(1)-N(2) | 87.3(5) | O(3)-Pt(2)-N(4) | 87.3(5) |
O(10)-Pt(1)-N(1) | 87.8(5) | O(11)-Pt(2)-N(3) | 86.4(5) |
N(1)-Pt(1)-N(2) | 93.3(6) | N(3)-Pt(2)-N(4) | 93.8(5) |
Average | 90.0 | Average | 90.0 |
W(1)-O(4)-W(2) | 146.2(6) | W(5)-O(19)-W(6) | 116.1(5) |