Pt complexes (μmol of Pt atom)

Reaction time (h)

H2 (μmol)

TONb

TMA-P-Pt (0.5)

1

5

58.7

189.4

235

758

TMA-Si-Pt (0.5)

1

5

34.3

130.4

137

522

TMA-Ge-Pt (0.5)

1

5

57.0

162.9

228

651

TMA-P-Pt (1.0)

1

5

84.6

252.6

167

505

TMA-Si-Pt (1.0)

1

5

56.0

166.2

112

332

TMA-Ge-Pt (1.0)

1

5

76.7

193.8

153

388

TMA-P-Pt (2.0)

1

5

90.2

301.4

90

301

TMA-Si-Pt (2.0)

1

5

86.1

207.5

86

208

TMA-Ge-Pt (2.0)

1

5

77.6

230.6

78

231

TMA-P-Pt (2.0)c

1

5

50.4

125.0

50

125

TMA-Si-Pt (2.0)c

1

5

35.1

79.3

35

79

TMA-Ge-Pt (2.0)c

1

5

47.9

102.4

48

102