Sample Introduction

(AOC 20i, Shimadzu, Japan)

Mode

Splitless

Injector Temperature

240˚C

Injection Volume

1 µL

Gas Chromatograph

(GC 2010Plus, Shimadzu, Japan)

Capillary Column

Shimadzu InertCap Wax (30.0 m × 0.25 mm × 0.25 µm film thickness)

Carrier Gas

Helium (99.999%)

Column Flow Rate

1.53 mL・min⁻¹

Oven Temperature Program

70˚C (held 3 min), ramped to 150˚C at 15˚C min⁻¹ (held 2 min), and a final ramp to 240˚C at 15˚C min⁻¹ (held 8 min)

Run Time

21.33 min

Mass Spectrometer

(QPMS 2010Ultra, Shimadzu, Japan)

Acquisition Mode

FASST

Mass Range (m/z)

35 - 400 amu

Solvent Delay

6.4 min

Source Temperature

200˚C

Transfer Line Temperature

240˚C

Electron Energy

70 eV