Inventory for the period 1930-1999 | Fluorspar (million tonnes) | TFA emissions (tonnes) |
Global fluorspar production | 191.9 |
|
Metspar and ceramic grade production, inorganic uses | 96.9 | 0 |
Acidspar grade production (at 97% minimum purity) for HF | 95.0 |
|
Losses due to HF yield from acidspar (assuming 97.5% purity) | 8.9 | 0 |
Overall availability of HF as CaF2 equivalent | 86.1 |
|
Identified uses of HF as CaF2 equivalent |
|
|
CFCs (CFC-11, 12, 113, 114, 115) | 14.6 | 0 |
HCFCs (non-feedstock): For CaF2 consumption HCFC-22, 123, 124, 141b, 142b. TFA emissions: HCFC-123, 124 | 5.6 | 16,100 |
HFCs: For CaF2 consumption: HFC-134a, 125, 143a. TFA emissions: HFC-134a, 227ea, 125, 143a | 1.1 | 6700 |
PTFE & other fluoropolymers. TFA emissions for PTFE degradation, estimated based on | 2.5 | 60 (A) 7300 (B) |
Halon 1211 (Fluoride for Halon 1301 is included in HCFC-22 F-efficiency) | 0.1 | 0 |
Anaesthetics: halothane, isoflurane, sevoflurane, desflurane | 0.1 | 23,600 |
Pesticides, assuming 100% yield of TFA (and assuming 90% efficiency of CaF2 utilisation). | 0.2 to 0.4 (~0.3) | 140,000 to 380,000 |
Pharmaceuticals—example fluoxetine (Prozac) maximum TFA | trivial | 5000 |
TFA manufacture, assumes all TFA manufactured equals TFA emissions (unlikely) | 0.03 | 30,000 |
Aluminium production | 25.3 | 0 |
SF6 and SOF2 | 0.3 | 0 |
Uranium processing | 2.3 | 0 |
Petroleum alkylation | 1.3 | 0 |
Niobium and tantalum (aqueous HF) | 1.0 | 0 |
Stainless steel pickling (aqueous HF) | 3.0 | 0 |
Inorganic fluorides (mainly aqueous HF) indicative estimate | 1.7 | 0 |
Total uses of HF as CaF2 equiv. | 59.2 |
|
Total TFA emissions Excl. pesticides & pharmaceuticals (C) |
| 84,000 (C) |
Incl. pesticides & pharmaceuticals (D) |
| 230,000 to 470,000 (D) |
TFA emissions are rounded up |
|
|
Total fluorspar production accounted for | 86% |
|
Other HF uses as CaF2 equivalent | 26.9 |
|