Inventory for the period 1930-1999

Fluorspar

(million tonnes)

TFA emissions

(tonnes)

Global fluorspar production

191.9

Metspar and ceramic grade production, inorganic uses

96.9

0

Acidspar grade production (at 97% minimum purity) for HF

95.0

Losses due to HF yield from acidspar (assuming 97.5% purity)

8.9

0

Overall availability of HF as CaF2 equivalent

86.1

Identified uses of HF as CaF2 equivalent

CFCs (CFC-11, 12, 113, 114, 115)

14.6

0

HCFCs (non-feedstock): For CaF2 consumption HCFC-22, 123, 124, 141b, 142b. TFA emissions: HCFC-123, 124

5.6

16,100

HFCs: For CaF2 consumption: HFC-134a, 125, 143a.

TFA emissions: HFC-134a, 227ea, 125, 143a

1.1

6700

PTFE & other fluoropolymers. TFA emissions for PTFE degradation, estimated based on Cui et al., 2019 methodology (A) and from feedstock emissions: Hexafluoropropene (HFP) & HCFC-133a (B).

2.5

60 (A)

7300 (B)

Halon 1211 (Fluoride for Halon 1301 is included in HCFC-22 F-efficiency)

0.1

0

Anaesthetics: halothane, isoflurane, sevoflurane, desflurane

0.1

23,600

Pesticides, assuming 100% yield of TFA (and assuming 90% efficiency of CaF2 utilisation).

0.2 to 0.4 (~0.3)

140,000 to

380,000

Pharmaceuticals—example fluoxetine (Prozac) maximum TFA

trivial

5000

TFA manufacture, assumes all TFA manufactured equals TFA emissions (unlikely)

0.03

30,000

Aluminium production

25.3

0

SF6 and SOF2

0.3

0

Uranium processing

2.3

0

Petroleum alkylation

1.3

0

Niobium and tantalum (aqueous HF)

1.0

0

Stainless steel pickling (aqueous HF)

3.0

0

Inorganic fluorides (mainly aqueous HF) indicative estimate

1.7

0

Total uses of HF as CaF2 equiv.

59.2

Total TFA emissions Excl. pesticides & pharmaceuticals (C)

84,000 (C)

Incl. pesticides & pharmaceuticals (D)

230,000 to 470,000 (D)

TFA emissions are rounded up

Total fluorspar production accounted for

86%

Other HF uses as CaF2 equivalent

26.9