Complex

Stage

Method

Parameter

r

E

(J・mol−1)

A

(s−1)

ΔS

(J・mol−1・K−1)

ΔH

(J・mol−1)

ΔG

(J・mol−1)

(III)

1st

CR

HM

3.23 × 105

3.51 × 105

1.82 × 1033

2.96 × 1036

3.88 × 102

4.49 × 102

3.19 × 105

3.47 × 105

1.31 × 105

1.29 × 105

0.9984

0.9989

(IIIa)

1st

CR

HM

4.56 × 104

5.49 × 104

1.31 × 102

2.02 × 103

−2.09 × 102

−1.86 × 102

4.13 × 104

5.05 × 104

1.50 × 105

1.47 × 105

0.9988

0.9953

(IIIb)

3st

CR

HM

1.67 × 105

2.13 × 105

5.30 × 105

5.28 × 107

−1.46 × 102

−1.08 × 102

1.57 × 105

2.04 × 105

3.20 × 105

3.24 × 105

0.9993

0.9985

(IIIc)

1st

CR

HM

1.95 × 105

2.06 × 105

5.85 × 1018

1.77 × 1020

1.10 × 102

1.39 × 102

1.91 × 105

2.02 × 105

1.37 × 105

1.34 × 105

0.9992

0.9974

(IIId)

1st

CR

HM

8.08 × 104

9.84 × 104

3.72 × 106

2.60 × 108

−1.23 × 102

−8.81 × 101

7.66 × 104

9.43 × 104

1.38 × 105

1. 38 × 105

0.9984

0.9984