Complex | Stage | Method | Parameter | r | ||||
E (J・mol−1) | A (s−1) | ΔS (J・mol−1・K−1) | ΔH (J・mol−1) | ΔG (J・mol−1) | ||||
(II) | 1st | CR HM | 1.79 × 105 1.54 × 105 | 1.94 × 1017 7.15 × 1014 | 8.20 × 101 3.54 × 101 | 1.75 × 105 1.50 × 105 | 1.35 × 105 1.33 × 105 | 0.9997 0.9992 |
(IIa) | 1st | CR HM | 4.70 × 104 6.65 × 104 | 1.40 × 102 4.13 × 104 | −2.08 × 102 −1.61 × 102 | 4.27 × 104 6.22 × 104 | 1.50 × 105 1.45 × 105 | 0.9963 0.9956 |
(IIb) | 1st | CR HM | 6.07 × 104 6.87 × 104 | 2.32 × 103 2.35 × 104 | −1.86 × 102 −1.66 × 102 | 5.61 × 104 6.42 × 104 | 1.58 × 105 1.55 × 105 | 0.9931 0.9918 |
(IIc) | 1st | CR HM | 4.58 × 104 4.65 × 105 | 1.17 × 1047 1.20 × 1048 | 6.52 × 102 6.70 × 102 | 4.54 × 105 4.61 × 105 | 1.33 × 105 1.30 × 105 | 0.9977 0.9982 |
(IId) | 1st | CR HM | 2.76 × 104 2.95 × 105 | 1.68 × 1027 1.77 × 1029 | 2.72 × 102 3.11 × 102 | 2.72 × 105 2.90 × 105 | 1.36 × 105 1. 35 × 105 | 0.9950 0.9945 |