Complex

Stage

Method

Parameter

r

E

(J・mol−1)

A

(s−1)

ΔS

(J・mol−1・K−1)

ΔH

(J・mol−1)

ΔG

(J・mol−1)

(II)

1st

CR

HM

1.79 × 105

1.54 × 105

1.94 × 1017

7.15 × 1014

8.20 × 101

3.54 × 101

1.75 × 105

1.50 × 105

1.35 × 105

1.33 × 105

0.9997

0.9992

(IIa)

1st

CR

HM

4.70 × 104

6.65 × 104

1.40 × 102

4.13 × 104

−2.08 × 102

−1.61 × 102

4.27 × 104

6.22 × 104

1.50 × 105

1.45 × 105

0.9963

0.9956

(IIb)

1st

CR

HM

6.07 × 104

6.87 × 104

2.32 × 103

2.35 × 104

−1.86 × 102

−1.66 × 102

5.61 × 104

6.42 × 104

1.58 × 105

1.55 × 105

0.9931

0.9918

(IIc)

1st

CR

HM

4.58 × 104

4.65 × 105

1.17 × 1047

1.20 × 1048

6.52 × 102

6.70 × 102

4.54 × 105

4.61 × 105

1.33 × 105

1.30 × 105

0.9977

0.9982

(IId)

1st

CR

HM

2.76 × 104

2.95 × 105

1.68 × 1027

1.77 × 1029

2.72 × 102

3.11 × 102

2.72 × 105

2.90 × 105

1.36 × 105

1. 35 × 105

0.9950

0.9945