Complex

Stage

Method

Parameter

r

E

(J mol−1)

A

(s−1)

ΔS

(J・mol−1・K−1)

ΔH

(J・mol−1)

ΔG

(J・mol−1)

(I)

1st

CR

HM

1.12 × 105

1.28 × 105

1.07 × 1010

1.50 × 1012

−5.68 × 101

−1.58 × 101

1.08 × 105

1.24 × 105

1.35 × 105

1.32 × 105

0.9981

0.9961

(Ia)

1st

CR

HM

5.14 × 104

6.33 × 104

7.99 × 103

6.60 × 103

−1.75 × 102

−1.77 × 102

4.68 × 104

5.87 × 104

1.43 × 105

1.56 × 105

0.9920

0.9929

(Ib)

1st

CR

HM

1.10 × 105

1.31 × 105

7.01 × 109

2.96 × 1012

−6.04 × 101

−1.01 × 101

1.06 × 105

1.27 × 105

1.35 × 105

1. 31 × 105

0.9995

0.9991

(Ic)

1st

CR

HM

8.04 × 104

1.07 × 105

7.21 × 105

2.29 × 108

−1.38 × 102

−8.98 × 101

7.59 × 104

1.02 × 105

1.50 × 105

1.51 × 105

0.9968

0.9985

(Id)

1st

CR

HM

8.61 × 104

1.71 × 105

1.65 × 107

32.75 × 109

−1.11 × 102

−6.59 × 101

8.2 × 104

1.05 × 105

1.37 × 105

1. 38 × 105

0.9938

0.9955