Complex | Stage | Method | Parameter | r | ||||
E (J mol−1) | A (s−1) | ΔS (J・mol−1・K−1) | ΔH (J・mol−1) | ΔG (J・mol−1) | ||||
(I) | 1st | CR HM | 1.12 × 105 1.28 × 105 | 1.07 × 1010 1.50 × 1012 | −5.68 × 101 −1.58 × 101 | 1.08 × 105 1.24 × 105 | 1.35 × 105 1.32 × 105 | 0.9981 0.9961 |
(Ia) | 1st | CR HM | 5.14 × 104 6.33 × 104 | 7.99 × 103 6.60 × 103 | −1.75 × 102 −1.77 × 102 | 4.68 × 104 5.87 × 104 | 1.43 × 105 1.56 × 105 | 0.9920 0.9929 |
(Ib) | 1st | CR HM | 1.10 × 105 1.31 × 105 | 7.01 × 109 2.96 × 1012 | −6.04 × 101 −1.01 × 101 | 1.06 × 105 1.27 × 105 | 1.35 × 105 1. 31 × 105 | 0.9995 0.9991 |
(Ic) | 1st | CR HM | 8.04 × 104 1.07 × 105 | 7.21 × 105 2.29 × 108 | −1.38 × 102 −8.98 × 101 | 7.59 × 104 1.02 × 105 | 1.50 × 105 1.51 × 105 | 0.9968 0.9985 |
(Id) | 1st | CR HM | 8.61 × 104 1.71 × 105 | 1.65 × 107 32.75 × 109 | −1.11 × 102 −6.59 × 101 | 8.2 × 104 1.05 × 105 | 1.37 × 105 1. 38 × 105 | 0.9938 0.9955 |